發布時間：2026-04-14 21:31:43 人氣：300249 來源：川工密封
1.整體腐蝕和局部腐蝕。綜合腐蝕，即與介質接觸的零件表麵發生均勻腐蝕，其特點是零件重量減輕，甚至完全腐蝕；失去力量；降低硬度。如1Cr18Ni9Ti不(bu)鏽(xiu)鋼(gang)製(zhi)成(cheng)的(de)多(duo)彈(dan)簧(huang)，在(zai)稀(xi)硫(liu)酸(suan)中(zhong)使(shi)用(yong)會(hui)出(chu)現(xian)這(zhe)種(zhong)情(qing)況(kuang)。局(ju)部(bu)腐(fu)蝕(shi)可(ke)以(yi)簡(jian)單(dan)地(di)通(tong)過(guo)零(ling)件(jian)上(shang)的(de)腐(fu)蝕(shi)點(dian)和(he)孔(kong)來(lai)識(shi)別(bie)。局(ju)部(bu)腐(fu)蝕(shi)是(shi)多(duo)相(xiang)合(he)金(jin)中(zhong)的(de)某(mou)一(yi)相(xiang)或(huo)單(dan)相(xiang)固(gu)溶(rong)體(ti)中(zhong)的(de)某(mou)一(yi)元(yuan)素(su)被(bei)介(jie)質(zhi)選(xuan)擇(ze)性(xing)溶(rong)解(jie)的(de)腐(fu)蝕(shi)形(xing)式(shi)。如(ru)鈷(gu)基(ji)硬(ying)質(zhi)合(he)金(jin)在(zai)高(gao)溫(wen)強(qiang)堿(jian)條(tiao)件(jian)下(xia)使(shi)用(yong)，粘(zhan)結(jie)相(xiang)金(jin)屬(shu)鈷(gu)容(rong)易(yi)被(bei)腐(fu)蝕(shi)，硬(ying)質(zhi)相(xiang)碳(tan)化(hua)鎢(wu)骨(gu)架(jia)失(shi)去(qu)強(qiang)度(du)，在(zai)機(ji)械(xie)力(li)的(de)作(zuo)用(yong)下(xia)導(dao)致(zhi)晶(jing)粒(li)剝(bo)落(luo)。作(zuo)為(wei)另(ling)一(yi)個(ge)例(li)子(zi)，由(you)於(yu)遊(you)離(li)矽(gui)的(de)腐(fu)蝕(shi)，反(fan)應(ying)燒(shao)結(jie)碳(tan)化(hua)矽(gui)的(de)表(biao)麵(mian)顯(xian)示(shi)麻(ma)點(dian)(PH>10時).
fushiduimifengjiandexingnengyouhendayingxiang。youyumifengbizhujidelingjiangengxiao，jingdugenggao，suoyitongchangxuanzebizhujimifengnaifushidecailiao。duiyuyujiezhizhijiejiechudemifengjian，kecankaoxiangguanfushishoucezhongdeshujuxuanzeheshidecailiao。raner，zhexieshujukenengyu廈門機械密封係統中使用的條件不一致，因為它們大多是靜態條件下的腐蝕數據，並且工藝流程中的介質包含雜質或二次化合物。經驗表明，壓力、溫度和滑動速度都會加速腐蝕。隨著溫度的升高，密封件的腐蝕速率呈指數增長。
在zai處chu理li強qiang腐fu蝕shi性xing流liu體ti時shi，采cai用yong外wai密mi封feng或huo雙shuang端duan密mi封feng可ke以yi最zui大da限xian度du地di減jian少shao腐fu蝕shi對dui密mi封feng的de影ying響xiang，因yin為wei它ta與yu工gong藝yi流liu體ti接jie觸chu的de零ling件jian數shu量liang最zui少shao。這zhe也ye是shi在zai強qiang腐fu蝕shi條tiao件jian下xia選xuan擇ze密mi封feng結jie構gou最zui古gu老lao的de窯yao理li之zhi一yi。
2.應力腐蝕。應力腐蝕是金屬材料在應力作用下在腐蝕環境中的腐蝕現象。無論是外載荷還是殘餘應力，都會加劇腐蝕。奧氏體不鏽鋼、銅tong合he金jin等deng。容rong易yi產chan生sheng應ying力li腐fu蝕shi。在zai應ying力li腐fu蝕shi過guo程cheng中zhong，一yi般ban在zai金jin屬shu表biao麵mian形xing成cheng選xuan擇ze性xing腐fu蝕shi槽cao，然ran後hou繼ji續xu局ju部bu腐fu蝕shi，最zui後hou在zai應ying力li作zuo用yong下xia從cong槽cao底di產chan生sheng裂lie紋wen。典dian型xing的de例li子zi是shi104型廈門機械密封的傳動套筒，由1Cr18Ni9Tizhicheng。zaianshuibengzhongshiyongshi，chuandongtaotongdechuandongerhuanzuirongyichanshengyinglifushiliewen，congersunhuaierhuan。suoyibaaoerdinghuanchengshixinerpiankeyifangzhizhezhongyinglifushi。
3.jiezhifushi。mifengjianheliutizhijiandegaosuyundongdaozhijiechubiaomianshangdeweixiaobujunyun。dangliutiweifushixingjiezhishi，huijiasumifengjiechumiandehuaxuefanying，youshiyouyi，youshiyouhai。ruguoxingchengdeyanghuacengbeipohuai，jiuhuifashengfushi。mosunhemoshijiaotizuoyongduicailiaozaochengdesunshangchengweimoshi。tongchang，mosundui廈門機械密封的非主要部件造成的損壞，如彈簧座、推環、環huan座zuo等deng。並bing不bu能neng迅xun速su反fan映ying密mi封feng性xing能neng的de變bian化hua，但dan卻que是shi摩mo擦ca副fu失shi效xiao的de主zhu要yao形xing式shi之zhi一yi。因yin此ci，在zai腔qiang體ti的de腐fu蝕shi介jie質zhi中zhong，摩mo擦ca副fu應ying由you耐nai腐fu蝕shi性xing好hao的de材cai料liao製zhi成cheng。例li如ru，使shi用yong99.5%高純度氧化鋁陶瓷或不含遊離矽的熱壓燒結碳化矽。
4.間jian隙xi腐fu蝕shi。當dang介jie質zhi處chu於yu金jin屬shu與yu金jin屬shu或huo非fei金jin屬shu構gou件jian之zhi間jian，且qie存cun在zai小xiao間jian隙xi時shi，由you於yu介jie質zhi處chu於yu停ting滯zhi狀zhuang態tai，間jian隙xi內nei金jin屬shu的de腐fu蝕shi會hui加jia速su，這zhe種zhong現xian象xiang稱cheng為wei間jian隙xi腐fu蝕shi。例li如ru廈門機械密封彈簧座與軸之間的溝槽或衝蝕點，補償環輔助密封環與軸之間的溝槽或衝蝕點(這裏當然有微動磨損)jiushidianxingdelizi。yuanyinshijietouneidejiezhichuyutingzhizhuangtai，shidecanyufushifanyingdewuzhinanyijiarujietounei，jietouneidefushichanwunanyixiangwaikuosan。suizhefushidejinxing，jietouzhongdejiezhizaichengfennongduhePH值zhi上shang與yu整zheng個ge介jie質zhi越yue來lai越yue不bu同tong，導dao致zhi接jie頭tou中zhong金jin屬shu表biao麵mian的de腐fu蝕shi加jia劇ju。間jian隙xi腐fu蝕shi對dui密mi封feng性xing能neng非fei常chang有you害hai。密mi封feng圈quan與yu雙shuang軸zhou之zhi間jian的de凹ao槽cao會hui導dao致zhi補bu償chang環huan無wu法fa軸zhou向xiang位wei移yi，失shi去qu隨sui動dong性xing，導dao致zhi端duan麵mian分fen離li和he泄xie漏lou。間jian隙xi腐fu蝕shi通tong常chang可ke以yi通tong過guo適shi當dang的de材cai料liao選xuan擇ze和he合he理li的de結jie構gou設she計ji來lai緩huan解jie。比bi如ru選xuan擇ze抗kang間jian隙xi腐fu蝕shi性xing能neng好hao的de材cai料liao；在zai結jie構gou設she計ji中zhong，應ying盡jin可ke能neng避bi免mian液ye體ti積ji聚ju的de間jian隙xi和he死si區qu。采cai用yong自zi衝chong洗xi循xun環huan，使shi密mi封feng腔qiang內nei的de介jie質zhi處chu於yu不bu斷duan更geng換huan和he流liu動dong的de狀zhuang態tai，防fang止zhi介jie質zhi成cheng分fen的de濃nong度du變bian化hua；duiyuchangqitingyongdebeng，yingjishipaichujijudeyetideng。bukenengwanquanxiaochujiegoushangdechaju。suoyiyibancaiyongfanghuzhoucheng，keyizaimifengquananzhuangbuweipentunaifushicailiaolaifangzhi。
5.電化學腐蝕。事實上，廈門機械密封的各種腐蝕形式或多或少都與銅的電化學腐蝕有關。就廈門機械密封摩(mo)擦(ca)副(fu)而(er)言(yan)，它(ta)們(men)經(jing)常(chang)受(shou)到(dao)電(dian)化(hua)學(xue)腐(fu)蝕(shi)的(de)損(sun)害(hai)，因(yin)為(wei)摩(mo)擦(ca)副(fu)中(zhong)通(tong)常(chang)使(shi)用(yong)不(bu)同(tong)的(de)材(cai)料(liao)。當(dang)它(ta)們(men)處(chu)於(yu)電(dian)解(jie)質(zhi)溶(rong)液(ye)中(zhong)時(shi)，不(bu)同(tong)材(cai)料(liao)接(jie)觸(chu)時(shi)會(hui)出(chu)現(xian)點(dian)耦(ou)合(he)效(xiao)應(ying)，即(ji)一(yi)種(zhong)材(cai)料(liao)的(de)腐(fu)蝕(shi)得(de)到(dao)促(cu)進(jin)，另(ling)一(yi)種(zhong)材(cai)料(liao)的(de)腐(fu)蝕(shi)得(de)到(dao)抑(yi)製(zhi)。例(li)如(ru)，當(dang)銅(tong)和(he)鎳(nie)鉻(ge)鋼(gang)用(yong)於(yu)氧(yang)化(hua)介(jie)質(zhi)時(shi)，鎳(nie)鎘(ge)鋼(gang)被(bei)電(dian)離(li)和(he)分(fen)解(jie)。鹽(yan)水(shui)、海水、稀鹽酸、稀硫酸等。都是典型的電解質溶液，密封件容易發生電化學腐蝕。所以最好選擇材料或者電位相近的陶瓷，以及玻璃纖維填充的PTFE。
