發布時間：2026-04-27 11:08:46 人氣：306856 來源：川工密封
1.整體腐蝕和局部腐蝕。綜合腐蝕，即與介質接觸的零件表麵發生均勻腐蝕，其特點是零件重量減輕，甚至完全腐蝕；失去力量；降低硬度。如1Cr18Ni9Tibuxiugangzhichengdeduodanhuang，zaixiliusuanzhongshiyonghuichuxianzhezhongqingkuang。jubufushikeyijiandanditongguolingjianshangdefushidianhekonglaishibie。jubufushishiduoxianghejinzhongdemouyixianghuodanxianggurongtizhongdemouyiyuansubeijiezhixuanzexingrongjiedefushixingshi。rugujiyingzhihejinzaigaowenqiangjiantiaojianxiashiyong，zhanjiexiangjinshugurongyibeifushi，yingzhixiangtanhuawugujiashiquqiangdu，zaijixielidezuoyongxiadaozhijingliboluo。zuoweilingyigelizi，youyuyouliguidefushi，fanyingshaojietanhuaguidebiaomianxianshimadian(PH>10時).
腐fu蝕shi對dui密mi封feng件jian的de性xing能neng有you很hen大da影ying響xiang。由you於yu密mi封feng比bi主zhu機ji的de零ling件jian更geng小xiao，精jing度du更geng高gao，所suo以yi通tong常chang選xuan擇ze比bi主zhu機ji密mi封feng耐nai腐fu蝕shi的de材cai料liao。對dui於yu與yu介jie質zhi直zhi接jie接jie觸chu的de密mi封feng件jian，可ke參can考kao相xiang關guan腐fu蝕shi手shou冊ce中zhong的de數shu據ju選xuan擇ze合he適shi的de材cai料liao。然ran而er，這zhe些xie數shu據ju可ke能neng與yu路南機械密封係統中使用的條件不一致，因為它們大多是靜態條件下的腐蝕數據，並且工藝流程中的介質包含雜質或二次化合物。經驗表明，壓力、溫度和滑動速度都會加速腐蝕。隨著溫度的升高，密封件的腐蝕速率呈指數增長。
在(zai)處(chu)理(li)強(qiang)腐(fu)蝕(shi)性(xing)流(liu)體(ti)時(shi)，采(cai)用(yong)外(wai)密(mi)封(feng)或(huo)雙(shuang)端(duan)密(mi)封(feng)可(ke)以(yi)最(zui)大(da)限(xian)度(du)地(di)減(jian)少(shao)腐(fu)蝕(shi)對(dui)密(mi)封(feng)的(de)影(ying)響(xiang)，因(yin)為(wei)它(ta)與(yu)工(gong)藝(yi)流(liu)體(ti)接(jie)觸(chu)的(de)零(ling)件(jian)數(shu)量(liang)最(zui)少(shao)。這(zhe)也(ye)是(shi)在(zai)強(qiang)腐(fu)蝕(shi)條(tiao)件(jian)下(xia)選(xuan)擇(ze)密(mi)封(feng)結(jie)構(gou)最(zui)古(gu)老(lao)的(de)窯(yao)理(li)之(zhi)一(yi)。
2.應力腐蝕。應力腐蝕是金屬材料在應力作用下在腐蝕環境中的腐蝕現象。無論是外載荷還是殘餘應力，都會加劇腐蝕。奧氏體不鏽鋼、銅(tong)合(he)金(jin)等(deng)。容(rong)易(yi)產(chan)生(sheng)應(ying)力(li)腐(fu)蝕(shi)。在(zai)應(ying)力(li)腐(fu)蝕(shi)過(guo)程(cheng)中(zhong)，一(yi)般(ban)在(zai)金(jin)屬(shu)表(biao)麵(mian)形(xing)成(cheng)選(xuan)擇(ze)性(xing)腐(fu)蝕(shi)槽(cao)，然(ran)後(hou)繼(ji)續(xu)局(ju)部(bu)腐(fu)蝕(shi)，最(zui)後(hou)在(zai)應(ying)力(li)作(zuo)用(yong)下(xia)從(cong)槽(cao)底(di)產(chan)生(sheng)裂(lie)紋(wen)。典(dian)型(xing)的(de)例(li)子(zi)是(shi)104型路南機械密封的傳動套筒，由1Cr18Ni9Ti製(zhi)成(cheng)。在(zai)氨(an)水(shui)泵(beng)中(zhong)使(shi)用(yong)時(shi)，傳(chuan)動(dong)套(tao)筒(tong)的(de)傳(chuan)動(dong)耳(er)環(huan)最(zui)容(rong)易(yi)產(chan)生(sheng)應(ying)力(li)腐(fu)蝕(shi)裂(lie)紋(wen)，從(cong)而(er)損(sun)壞(huai)耳(er)環(huan)。所(suo)以(yi)把(ba)凹(ao)耳(er)釘(ding)換(huan)成(cheng)實(shi)心(xin)耳(er)片(pian)可(ke)以(yi)防(fang)止(zhi)這(zhe)種(zhong)應(ying)力(li)腐(fu)蝕(shi)。
3.介jie質zhi腐fu蝕shi。密mi封feng件jian和he流liu體ti之zhi間jian的de高gao速su運yun動dong導dao致zhi接jie觸chu表biao麵mian上shang的de微wei小xiao不bu均jun勻yun。當dang流liu體ti為wei腐fu蝕shi性xing介jie質zhi時shi，會hui加jia速su密mi封feng接jie觸chu麵mian的de化hua學xue反fan應ying，有you時shi有you益yi，有you時shi有you害hai。如ru果guo形xing成cheng的de氧yang化hua層ceng被bei破po壞huai，就jiu會hui發fa生sheng腐fu蝕shi。磨mo損sun和he磨mo蝕shi交jiao替ti作zuo用yong對dui材cai料liao造zao成cheng的de損sun傷shang稱cheng為wei磨mo蝕shi。通tong常chang，磨mo損sun對dui路南機械密封的非主要部件造成的損壞，如彈簧座、推環、huanzuodeng。bingbunengxunsufanyingmifengxingnengdebianhua，danqueshimocafushixiaodezhuyaoxingshizhiyi。yinci，zaiqiangtidefushijiezhizhong，mocafuyingyounaifushixinghaodecailiaozhicheng。liru，shiyong99.5%高純度氧化鋁陶瓷或不含遊離矽的熱壓燒結碳化矽。
4.間(jian)隙(xi)腐(fu)蝕(shi)。當(dang)介(jie)質(zhi)處(chu)於(yu)金(jin)屬(shu)與(yu)金(jin)屬(shu)或(huo)非(fei)金(jin)屬(shu)構(gou)件(jian)之(zhi)間(jian)，且(qie)存(cun)在(zai)小(xiao)間(jian)隙(xi)時(shi)，由(you)於(yu)介(jie)質(zhi)處(chu)於(yu)停(ting)滯(zhi)狀(zhuang)態(tai)，間(jian)隙(xi)內(nei)金(jin)屬(shu)的(de)腐(fu)蝕(shi)會(hui)加(jia)速(su)，這(zhe)種(zhong)現(xian)象(xiang)稱(cheng)為(wei)間(jian)隙(xi)腐(fu)蝕(shi)。例(li)如(ru)路南機械密封彈簧座與軸之間的溝槽或衝蝕點，補償環輔助密封環與軸之間的溝槽或衝蝕點(這裏當然有微動磨損)就jiu是shi典dian型xing的de例li子zi。原yuan因yin是shi接jie頭tou內nei的de介jie質zhi處chu於yu停ting滯zhi狀zhuang態tai，使shi得de參can與yu腐fu蝕shi反fan應ying的de物wu質zhi難nan以yi加jia入ru接jie頭tou內nei，接jie頭tou內nei的de腐fu蝕shi產chan物wu難nan以yi向xiang外wai擴kuo散san。隨sui著zhe腐fu蝕shi的de進jin行xing，接jie頭tou中zhong的de介jie質zhi在zai成cheng分fen濃nong度du和hePHzhishangyuzhenggejiezhiyuelaiyuebutong，daozhijietouzhongjinshubiaomiandefushijiaju。jianxifushiduimifengxingnengfeichangyouhai。mifengquanyushuangzhouzhijiandeaocaohuidaozhibuchanghuanwufazhouxiangweiyi，shiqusuidongxing，daozhiduanmianfenlihexielou。jianxifushitongchangkeyitongguoshidangdecailiaoxuanzehehelidejiegoushejilaihuanjie。biruxuanzekangjianxifushixingnenghaodecailiao；zaijiegoushejizhong，yingjinkenengbimianyetijijudejianxihesiqu。caiyongzichongxixunhuan，shimifengqiangneidejiezhichuyubuduangenghuanheliudongdezhuangtai，fangzhijiezhichengfendenongdubianhua；duiyuchangqitingyongdebeng，yingjishipaichujijudeyetideng。bukenengwanquanxiaochujiegoushangdechaju。suoyiyibancaiyongfanghuzhoucheng，keyizaimifengquananzhuangbuweipentunaifushicailiaolaifangzhi。
5.電化學腐蝕。事實上，路南機械密封的各種腐蝕形式或多或少都與銅的電化學腐蝕有關。就路南機械密封摩(mo)擦(ca)副(fu)而(er)言(yan)，它(ta)們(men)經(jing)常(chang)受(shou)到(dao)電(dian)化(hua)學(xue)腐(fu)蝕(shi)的(de)損(sun)害(hai)，因(yin)為(wei)摩(mo)擦(ca)副(fu)中(zhong)通(tong)常(chang)使(shi)用(yong)不(bu)同(tong)的(de)材(cai)料(liao)。當(dang)它(ta)們(men)處(chu)於(yu)電(dian)解(jie)質(zhi)溶(rong)液(ye)中(zhong)時(shi)，不(bu)同(tong)材(cai)料(liao)接(jie)觸(chu)時(shi)會(hui)出(chu)現(xian)點(dian)耦(ou)合(he)效(xiao)應(ying)，即(ji)一(yi)種(zhong)材(cai)料(liao)的(de)腐(fu)蝕(shi)得(de)到(dao)促(cu)進(jin)，另(ling)一(yi)種(zhong)材(cai)料(liao)的(de)腐(fu)蝕(shi)得(de)到(dao)抑(yi)製(zhi)。例(li)如(ru)，當(dang)銅(tong)和(he)鎳(nie)鉻(ge)鋼(gang)用(yong)於(yu)氧(yang)化(hua)介(jie)質(zhi)時(shi)，鎳(nie)鎘(ge)鋼(gang)被(bei)電(dian)離(li)和(he)分(fen)解(jie)。鹽(yan)水(shui)、海水、稀鹽酸、稀硫酸等。都是典型的電解質溶液，密封件容易發生電化學腐蝕。所以最好選擇材料或者電位相近的陶瓷，以及玻璃纖維填充的PTFE。
