梁山機械密封的腐蝕類型

　　1.整體腐蝕和局部腐蝕。綜合腐蝕，即與介質接觸的零件表麵發生均勻腐蝕，其特點是零件重量減輕，甚至完全腐蝕
；失去力量；降低硬度。如1Cr18Ni9Tibuxiugangzhichengdeduodanhuang
，zaixiliusuanzhongshiyonghuichuxianzhezhongqingkuang。jubufushikeyijiandanditongguolingjianshangdefushidianhekonglaishibie。jubufushishiduoxianghejinzhongdemouyixianghuodanxianggurongtizhongdemouyiyuansubeijiezhixuanzexingrongjiedefushixingshi。rugujiyingzhihejinzaigaowenqiangjiantiaojianxiashiyong，zhanjiexiangjinshugurongyibeifushi，yingzhixiangtanhuawugujiashiquqiangdu，zaijixielidezuoyongxiadaozhijingliboluo。zuoweilingyigelizi，youyuyouliguidefushi，fanyingshaojietanhuaguidebiaomianxianshimadian(PH>10時).
　　腐(fu)蝕(shi)對(dui)密(mi)封(feng)件(jian)的(de)性(xing)能(neng)有(you)很(hen)大(da)影(ying)響(xiang)。由(you)於(yu)密(mi)封(feng)比(bi)主(zhu)機(ji)的(de)零(ling)件(jian)更(geng)小(xiao)，精(jing)度(du)更(geng)高(gao)，所(suo)以(yi)通(tong)常(chang)選(xuan)擇(ze)比(bi)主(zhu)機(ji)密(mi)封(feng)耐(nai)腐(fu)蝕(shi)的(de)材(cai)料(liao)。對(dui)於(yu)與(yu)介(jie)質(zhi)直(zhi)接(jie)接(jie)觸(chu)的(de)密(mi)封(feng)件(jian)，可(ke)參(can)考(kao)相(xiang)關(guan)腐(fu)蝕(shi)手(shou)冊(ce)中(zhong)的(de)數(shu)據(ju)選(xuan)擇(ze)合(he)適(shi)的(de)材(cai)料(liao)。然(ran)而(er)
，這(zhe)些(xie)數(shu)據(ju)可(ke)能(neng)與(yu)梁山機械密封係統中使用的條件不一致，因為它們大多是靜態條件下的腐蝕數據
，並且工藝流程中的介質包含雜質或二次化合物。經驗表明，壓力、溫度和滑動速度都會加速腐蝕。隨著溫度的升高，密封件的腐蝕速率呈指數增長。
　　zaichuliqiangfushixingliutishi
，caiyongwaimifenghuoshuangduanmifengkeyizuidaxiandudijianshaofushiduimifengdeyingxiang
，yinweitayugongyiliutijiechudelingjianshuliangzuishao。zheyeshizaiqiangfushitiaojianxiaxuanzemifengjiegouzuigulaodeyaolizhiyi。
　　2.應力腐蝕。應力腐蝕是金屬材料在應力作用下在腐蝕環境中的腐蝕現象。無論是外載荷還是殘餘應力，都會加劇腐蝕。奧氏體不鏽鋼
、tonghejindeng。rongyichanshengyinglifushi。zaiyinglifushiguochengzhong，yibanzaijinshubiaomianxingchengxuanzexingfushicao，ranhoujixujubufushi，zuihouzaiyinglizuoyongxiacongcaodichanshengliewen。dianxingdelizishi104型梁山機械密封的傳動套筒，由1Cr18Ni9Ti製zhi成cheng。在zai氨an水shui泵beng中zhong使shi用yong時shi
，傳chuan動dong套tao筒tong的de傳chuan動dong耳er環huan最zui容rong易yi產chan生sheng應ying力li腐fu蝕shi裂lie紋wen
，從cong而er損sun壞huai耳er環huan。所suo以yi把ba凹ao耳er釘ding換huan成cheng實shi心xin耳er片pian可ke以yi防fang止zhi這zhe種zhong應ying力li腐fu蝕shi。
　　3.介jie質zhi腐fu蝕shi。密mi封feng件jian和he流liu體ti之zhi間jian的de高gao速su運yun動dong導dao致zhi接jie觸chu表biao麵mian上shang的de微wei小xiao不bu均jun勻yun。當dang流liu體ti為wei腐fu蝕shi性xing介jie質zhi時shi，會hui加jia速su密mi封feng接jie觸chu麵mian的de化hua學xue反fan應ying，有you時shi有you益yi
，有you時shi有you害hai。如ru果guo形xing成cheng的de氧yang化hua層ceng被bei破po壞huai，就jiu會hui發fa生sheng腐fu蝕shi。磨mo損sun和he磨mo蝕shi交jiao替ti作zuo用yong對dui材cai料liao造zao成cheng的de損sun傷shang稱cheng為wei磨mo蝕shi。通tong常chang
，磨mo損sun對dui梁山機械密封的非主要部件造成的損壞，如彈簧座
、推環、huanzuodeng。bingbunengxunsufanyingmifengxingnengdebianhua
，danqueshimocafushixiaodezhuyaoxingshizhiyi。yinci，zaiqiangtidefushijiezhizhong，mocafuyingyounaifushixinghaodecailiaozhicheng。liru，shiyong99.5%高純度氧化鋁陶瓷或不含遊離矽的熱壓燒結碳化矽。
　　4.jianxifushi。dangjiezhichuyujinshuyujinshuhuofeijinshugoujianzhijian，qiecunzaixiaojianxishi

，youyujiezhichuyutingzhizhuangtai，jianxineijinshudefushihuijiasu，zhezhongxianxiangchengweijianxifushi。liru梁山機械密封彈簧座與軸之間的溝槽或衝蝕點，補償環輔助密封環與軸之間的溝槽或衝蝕點(這裏當然有微動磨損)就(jiu)是(shi)典(dian)型(xing)的(de)例(li)子(zi)。原(yuan)因(yin)是(shi)接(jie)頭(tou)內(nei)的(de)介(jie)質(zhi)處(chu)於(yu)停(ting)滯(zhi)狀(zhuang)態(tai)
，使(shi)得(de)參(can)與(yu)腐(fu)蝕(shi)反(fan)應(ying)的(de)物(wu)質(zhi)難(nan)以(yi)加(jia)入(ru)接(jie)頭(tou)內(nei)
，接(jie)頭(tou)內(nei)的(de)腐(fu)蝕(shi)產(chan)物(wu)難(nan)以(yi)向(xiang)外(wai)擴(kuo)散(san)。隨(sui)著(zhe)腐(fu)蝕(shi)的(de)進(jin)行(xing)，接(jie)頭(tou)中(zhong)的(de)介(jie)質(zhi)在(zai)成(cheng)分(fen)濃(nong)度(du)和(he)PHzhishangyuzhenggejiezhiyuelaiyuebutong，daozhijietouzhongjinshubiaomiandefushijiaju。jianxifushiduimifengxingnengfeichangyouhai。mifengquanyushuangzhouzhijiandeaocaohuidaozhibuchanghuanwufazhouxiangweiyi，shiqusuidongxing，daozhiduanmianfenlihexielou。jianxifushitongchangkeyitongguoshidangdecailiaoxuanzehehelidejiegoushejilaihuanjie。biruxuanzekangjianxifushixingnenghaodecailiao；在zai結jie構gou設she計ji中zhong
，應ying盡jin可ke能neng避bi免mian液ye體ti積ji聚ju的de間jian隙xi和he死si區qu。采cai用yong自zi衝chong洗xi循xun環huan，使shi密mi封feng腔qiang內nei的de介jie質zhi處chu於yu不bu斷duan更geng換huan和he流liu動dong的de狀zhuang態tai
，防fang止zhi介jie質zhi成cheng分fen的de濃nong度du變bian化hua；對(dui)於(yu)長(chang)期(qi)停(ting)用(yong)的(de)泵(beng)，應(ying)及(ji)時(shi)排(pai)出(chu)積(ji)聚(ju)的(de)液(ye)體(ti)等(deng)。不(bu)可(ke)能(neng)完(wan)全(quan)消(xiao)除(chu)結(jie)構(gou)上(shang)的(de)差(cha)距(ju)。所(suo)以(yi)一(yi)般(ban)采(cai)用(yong)防(fang)護(hu)軸(zhou)承(cheng)，可(ke)以(yi)在(zai)密(mi)封(feng)圈(quan)安(an)裝(zhuang)部(bu)位(wei)噴(pen)塗(tu)耐(nai)腐(fu)蝕(shi)材(cai)料(liao)來(lai)防(fang)止(zhi)。
　　5.電化學腐蝕。事實上
，梁山機械密封的各種腐蝕形式或多或少都與銅的電化學腐蝕有關。就梁山機械密封摩mo擦ca副fu而er言yan，它ta們men經jing常chang受shou到dao電dian化hua學xue腐fu蝕shi的de損sun害hai
，因yin為wei摩mo擦ca副fu中zhong通tong常chang使shi用yong不bu同tong的de材cai料liao。當dang它ta們men處chu於yu電dian解jie質zhi溶rong液ye中zhong時shi，不bu同tong材cai料liao接jie觸chu時shi會hui出chu現xian點dian耦ou合he效xiao應ying，即ji一yi種zhong材cai料liao的de腐fu蝕shi得de到dao促cu進jin
，另ling一yi種zhong材cai料liao的de腐fu蝕shi得de到dao抑yi製zhi。例li如ru，當dang銅tong和he鎳nie鉻ge鋼gang用yong於yu氧yang化hua介jie質zhi時shi
，鎳nie鎘ge鋼gang被bei電dian離li和he分fen解jie。鹽yan水shui、海水、稀鹽酸、稀硫酸等。都是典型的電解質溶液，密封件容易發生電化學腐蝕。所以最好選擇材料或者電位相近的陶瓷，以及玻璃纖維填充的PTFE。