古冶機械密封的腐蝕類型

　　1.整體腐蝕和局部腐蝕。綜合腐蝕
，即與介質接觸的零件表麵發生均勻腐蝕

，其特點是零件重量減輕
，甚至完全腐蝕

；失去力量
；降低硬度。如1Cr18Ni9Tibuxiugangzhichengdeduodanhuang
，zaixiliusuanzhongshiyonghuichuxianzhezhongqingkuang。jubufushikeyijiandanditongguolingjianshangdefushidianhekonglaishibie。jubufushishiduoxianghejinzhongdemouyixianghuodanxianggurongtizhongdemouyiyuansubeijiezhixuanzexingrongjiedefushixingshi。rugujiyingzhihejinzaigaowenqiangjiantiaojianxiashiyong，zhanjiexiangjinshugurongyibeifushi，yingzhixiangtanhuawugujiashiquqiangdu，zaijixielidezuoyongxiadaozhijingliboluo。zuoweilingyigelizi
，youyuyouliguidefushi，fanyingshaojietanhuaguidebiaomianxianshimadian(PH>10時).
　　腐fu蝕shi對dui密mi封feng件jian的de性xing能neng有you很hen大da影ying響xiang。由you於yu密mi封feng比bi主zhu機ji的de零ling件jian更geng小xiao，精jing度du更geng高gao

，所suo以yi通tong常chang選xuan擇ze比bi主zhu機ji密mi封feng耐nai腐fu蝕shi的de材cai料liao。對dui於yu與yu介jie質zhi直zhi接jie接jie觸chu的de密mi封feng件jian，可ke參can考kao相xiang關guan腐fu蝕shi手shou冊ce中zhong的de數shu據ju選xuan擇ze合he適shi的de材cai料liao。然ran而er，這zhe些xie數shu據ju可ke能neng與yu古冶機械密封係統中使用的條件不一致
，因為它們大多是靜態條件下的腐蝕數據
，並且工藝流程中的介質包含雜質或二次化合物。經驗表明，壓力、溫度和滑動速度都會加速腐蝕。隨著溫度的升高
，密封件的腐蝕速率呈指數增長。
　　zaichuliqiangfushixingliutishi，caiyongwaimifenghuoshuangduanmifengkeyizuidaxiandudijianshaofushiduimifengdeyingxiang
，yinweitayugongyiliutijiechudelingjianshuliangzuishao。zheyeshizaiqiangfushitiaojianxiaxuanzemifengjiegouzuigulaodeyaolizhiyi。
　　2.應力腐蝕。應力腐蝕是金屬材料在應力作用下在腐蝕環境中的腐蝕現象。無論是外載荷還是殘餘應力，都會加劇腐蝕。奧氏體不鏽鋼、銅(tong)合(he)金(jin)等(deng)。容(rong)易(yi)產(chan)生(sheng)應(ying)力(li)腐(fu)蝕(shi)。在(zai)應(ying)力(li)腐(fu)蝕(shi)過(guo)程(cheng)中(zhong)，一(yi)般(ban)在(zai)金(jin)屬(shu)表(biao)麵(mian)形(xing)成(cheng)選(xuan)擇(ze)性(xing)腐(fu)蝕(shi)槽(cao)
，然(ran)後(hou)繼(ji)續(xu)局(ju)部(bu)腐(fu)蝕(shi)


，最(zui)後(hou)在(zai)應(ying)力(li)作(zuo)用(yong)下(xia)從(cong)槽(cao)底(di)產(chan)生(sheng)裂(lie)紋(wen)。典(dian)型(xing)的(de)例(li)子(zi)是(shi)104型古冶機械密封的傳動套筒
，由1Cr18Ni9Ti製(zhi)成(cheng)。在(zai)氨(an)水(shui)泵(beng)中(zhong)使(shi)用(yong)時(shi)，傳(chuan)動(dong)套(tao)筒(tong)的(de)傳(chuan)動(dong)耳(er)環(huan)最(zui)容(rong)易(yi)產(chan)生(sheng)應(ying)力(li)腐(fu)蝕(shi)裂(lie)紋(wen)，從(cong)而(er)損(sun)壞(huai)耳(er)環(huan)。所(suo)以(yi)把(ba)凹(ao)耳(er)釘(ding)換(huan)成(cheng)實(shi)心(xin)耳(er)片(pian)可(ke)以(yi)防(fang)止(zhi)這(zhe)種(zhong)應(ying)力(li)腐(fu)蝕(shi)。
　　3.jiezhifushi。mifengjianheliutizhijiandegaosuyundongdaozhijiechubiaomianshangdeweixiaobujunyun。dangliutiweifushixingjiezhishi，huijiasumifengjiechumiandehuaxuefanying，youshiyouyi
，youshiyouhai。ruguoxingchengdeyanghuacengbeipohuai
，jiuhuifashengfushi。mosunhemoshijiaotizuoyongduicailiaozaochengdesunshangchengweimoshi。tongchang
，mosundui古冶機械密封的非主要部件造成的損壞
，如彈簧座、推環、huanzuodeng。bingbunengxunsufanyingmifengxingnengdebianhua，danqueshimocafushixiaodezhuyaoxingshizhiyi。yinci，zaiqiangtidefushijiezhizhong，mocafuyingyounaifushixinghaodecailiaozhicheng。liru
，shiyong99.5%高純度氧化鋁陶瓷或不含遊離矽的熱壓燒結碳化矽。
　　4.jianxifushi。dangjiezhichuyujinshuyujinshuhuofeijinshugoujianzhijian，qiecunzaixiaojianxishi
，youyujiezhichuyutingzhizhuangtai
，jianxineijinshudefushihuijiasu，zhezhongxianxiangchengweijianxifushi。liru古冶機械密封彈簧座與軸之間的溝槽或衝蝕點
，補償環輔助密封環與軸之間的溝槽或衝蝕點(這裏當然有微動磨損)就(jiu)是(shi)典(dian)型(xing)的(de)例(li)子(zi)。原(yuan)因(yin)是(shi)接(jie)頭(tou)內(nei)的(de)介(jie)質(zhi)處(chu)於(yu)停(ting)滯(zhi)狀(zhuang)態(tai)

，使(shi)得(de)參(can)與(yu)腐(fu)蝕(shi)反(fan)應(ying)的(de)物(wu)質(zhi)難(nan)以(yi)加(jia)入(ru)接(jie)頭(tou)內(nei)，接(jie)頭(tou)內(nei)的(de)腐(fu)蝕(shi)產(chan)物(wu)難(nan)以(yi)向(xiang)外(wai)擴(kuo)散(san)。隨(sui)著(zhe)腐(fu)蝕(shi)的(de)進(jin)行(xing)，接(jie)頭(tou)中(zhong)的(de)介(jie)質(zhi)在(zai)成(cheng)分(fen)濃(nong)度(du)和(he)PHzhishangyuzhenggejiezhiyuelaiyuebutong，daozhijietouzhongjinshubiaomiandefushijiaju。jianxifushiduimifengxingnengfeichangyouhai。mifengquanyushuangzhouzhijiandeaocaohuidaozhibuchanghuanwufazhouxiangweiyi

，shiqusuidongxing，daozhiduanmianfenlihexielou。jianxifushitongchangkeyitongguoshidangdecailiaoxuanzehehelidejiegoushejilaihuanjie。biruxuanzekangjianxifushixingnenghaodecailiao；在(zai)結(jie)構(gou)設(she)計(ji)中(zhong)，應(ying)盡(jin)可(ke)能(neng)避(bi)免(mian)液(ye)體(ti)積(ji)聚(ju)的(de)間(jian)隙(xi)和(he)死(si)區(qu)。采(cai)用(yong)自(zi)衝(chong)洗(xi)循(xun)環(huan)，使(shi)密(mi)封(feng)腔(qiang)內(nei)的(de)介(jie)質(zhi)處(chu)於(yu)不(bu)斷(duan)更(geng)換(huan)和(he)流(liu)動(dong)的(de)狀(zhuang)態(tai)，防(fang)止(zhi)介(jie)質(zhi)成(cheng)分(fen)的(de)濃(nong)度(du)變(bian)化(hua)；對dui於yu長chang期qi停ting用yong的de泵beng，應ying及ji時shi排pai出chu積ji聚ju的de液ye體ti等deng。不bu可ke能neng完wan全quan消xiao除chu結jie構gou上shang的de差cha距ju。所suo以yi一yi般ban采cai用yong防fang護hu軸zhou承cheng，可ke以yi在zai密mi封feng圈quan安an裝zhuang部bu位wei噴pen塗tu耐nai腐fu蝕shi材cai料liao來lai防fang止zhi。
　　5.電化學腐蝕。事實上，古冶機械密封的各種腐蝕形式或多或少都與銅的電化學腐蝕有關。就古冶機械密封摩mo擦ca副fu而er言yan，它ta們men經jing常chang受shou到dao電dian化hua學xue腐fu蝕shi的de損sun害hai，因yin為wei摩mo擦ca副fu中zhong通tong常chang使shi用yong不bu同tong的de材cai料liao。當dang它ta們men處chu於yu電dian解jie質zhi溶rong液ye中zhong時shi，不bu同tong材cai料liao接jie觸chu時shi會hui出chu現xian點dian耦ou合he效xiao應ying，即ji一yi種zhong材cai料liao的de腐fu蝕shi得de到dao促cu進jin，另ling一yi種zhong材cai料liao的de腐fu蝕shi得de到dao抑yi製zhi。例li如ru，當dang銅tong和he鎳nie鉻ge鋼gang用yong於yu氧yang化hua介jie質zhi時shi
，鎳nie鎘ge鋼gang被bei電dian離li和he分fen解jie。鹽yan水shui、海水、稀鹽酸、稀硫酸等。都是典型的電解質溶液
，密封件容易發生電化學腐蝕。所以最好選擇材料或者電位相近的陶瓷，以及玻璃纖維填充的PTFE。