固陽機械密封的腐蝕類型

　　1.整體腐蝕和局部腐蝕。綜合腐蝕，即與介質接觸的零件表麵發生均勻腐蝕，其特點是零件重量減輕
，甚至完全腐蝕；失去力量；降低硬度。如1Cr18Ni9Ti不bu鏽xiu鋼gang製zhi成cheng的de多duo彈dan簧huang，在zai稀xi硫liu酸suan中zhong使shi用yong會hui出chu現xian這zhe種zhong情qing況kuang。局ju部bu腐fu蝕shi可ke以yi簡jian單dan地di通tong過guo零ling件jian上shang的de腐fu蝕shi點dian和he孔kong來lai識shi別bie。局ju部bu腐fu蝕shi是shi多duo相xiang合he金jin中zhong的de某mou一yi相xiang或huo單dan相xiang固gu溶rong體ti中zhong的de某mou一yi元yuan素su被bei介jie質zhi選xuan擇ze性xing溶rong解jie的de腐fu蝕shi形xing式shi。如ru鈷gu基ji硬ying質zhi合he金jin在zai高gao溫wen強qiang堿jian條tiao件jian下xia使shi用yong，粘zhan結jie相xiang金jin屬shu鈷gu容rong易yi被bei腐fu蝕shi，硬ying質zhi相xiang碳tan化hua鎢wu骨gu架jia失shi去qu強qiang度du
，在zai機ji械xie力li的de作zuo用yong下xia導dao致zhi晶jing粒li剝bo落luo。作zuo為wei另ling一yi個ge例li子zi，由you於yu遊you離li矽gui的de腐fu蝕shi，反fan應ying燒shao結jie碳tan化hua矽gui的de表biao麵mian顯xian示shi麻ma點dian(PH>10時).
　　fushiduimifengjiandexingnengyouhendayingxiang。youyumifengbizhujidelingjiangengxiao，jingdugenggao
，suoyitongchangxuanzebizhujimifengnaifushidecailiao。duiyuyujiezhizhijiejiechudemifengjian，kecankaoxiangguanfushishoucezhongdeshujuxuanzeheshidecailiao。raner，zhexieshujukenengyu固陽機械密封係統中使用的條件不一致
，因為它們大多是靜態條件下的腐蝕數據，並且工藝流程中的介質包含雜質或二次化合物。經驗表明，壓力、溫度和滑動速度都會加速腐蝕。隨著溫度的升高，密封件的腐蝕速率呈指數增長。
　　zaichuliqiangfushixingliutishi
，caiyongwaimifenghuoshuangduanmifengkeyizuidaxiandudijianshaofushiduimifengdeyingxiang，yinweitayugongyiliutijiechudelingjianshuliangzuishao。zheyeshizaiqiangfushitiaojianxiaxuanzemifengjiegouzuigulaodeyaolizhiyi。
　　2.應力腐蝕。應力腐蝕是金屬材料在應力作用下在腐蝕環境中的腐蝕現象。無論是外載荷還是殘餘應力，都會加劇腐蝕。奧氏體不鏽鋼、tonghejindeng。rongyichanshengyinglifushi。zaiyinglifushiguochengzhong
，yibanzaijinshubiaomianxingchengxuanzexingfushicao
，ranhoujixujubufushi，zuihouzaiyinglizuoyongxiacongcaodichanshengliewen。dianxingdelizishi104型固陽機械密封的傳動套筒，由1Cr18Ni9Ti製zhi成cheng。在zai氨an水shui泵beng中zhong使shi用yong時shi，傳chuan動dong套tao筒tong的de傳chuan動dong耳er環huan最zui容rong易yi產chan生sheng應ying力li腐fu蝕shi裂lie紋wen，從cong而er損sun壞huai耳er環huan。所suo以yi把ba凹ao耳er釘ding換huan成cheng實shi心xin耳er片pian可ke以yi防fang止zhi這zhe種zhong應ying力li腐fu蝕shi。
　　3.介jie質zhi腐fu蝕shi。密mi封feng件jian和he流liu體ti之zhi間jian的de高gao速su運yun動dong導dao致zhi接jie觸chu表biao麵mian上shang的de微wei小xiao不bu均jun勻yun。當dang流liu體ti為wei腐fu蝕shi性xing介jie質zhi時shi，會hui加jia速su密mi封feng接jie觸chu麵mian的de化hua學xue反fan應ying
，有you時shi有you益yi，有you時shi有you害hai。如ru果guo形xing成cheng的de氧yang化hua層ceng被bei破po壞huai

，就jiu會hui發fa生sheng腐fu蝕shi。磨mo損sun和he磨mo蝕shi交jiao替ti作zuo用yong對dui材cai料liao造zao成cheng的de損sun傷shang稱cheng為wei磨mo蝕shi。通tong常chang，磨mo損sun對dui固陽機械密封的非主要部件造成的損壞，如彈簧座
、推環
、huanzuodeng。bingbunengxunsufanyingmifengxingnengdebianhua
，danqueshimocafushixiaodezhuyaoxingshizhiyi。yinci，zaiqiangtidefushijiezhizhong
，mocafuyingyounaifushixinghaodecailiaozhicheng。liru，shiyong99.5%高純度氧化鋁陶瓷或不含遊離矽的熱壓燒結碳化矽。
　　4.間jian隙xi腐fu蝕shi。當dang介jie質zhi處chu於yu金jin屬shu與yu金jin屬shu或huo非fei金jin屬shu構gou件jian之zhi間jian
，且qie存cun在zai小xiao間jian隙xi時shi
，由you於yu介jie質zhi處chu於yu停ting滯zhi狀zhuang態tai
，間jian隙xi內nei金jin屬shu的de腐fu蝕shi會hui加jia速su，這zhe種zhong現xian象xiang稱cheng為wei間jian隙xi腐fu蝕shi。例li如ru固陽機械密封彈簧座與軸之間的溝槽或衝蝕點，補償環輔助密封環與軸之間的溝槽或衝蝕點(這裏當然有微動磨損)就jiu是shi典dian型xing的de例li子zi。原yuan因yin是shi接jie頭tou內nei的de介jie質zhi處chu於yu停ting滯zhi狀zhuang態tai，使shi得de參can與yu腐fu蝕shi反fan應ying的de物wu質zhi難nan以yi加jia入ru接jie頭tou內nei
，接jie頭tou內nei的de腐fu蝕shi產chan物wu難nan以yi向xiang外wai擴kuo散san。隨sui著zhe腐fu蝕shi的de進jin行xing，接jie頭tou中zhong的de介jie質zhi在zai成cheng分fen濃nong度du和hePH值zhi上shang與yu整zheng個ge介jie質zhi越yue來lai越yue不bu同tong，導dao致zhi接jie頭tou中zhong金jin屬shu表biao麵mian的de腐fu蝕shi加jia劇ju。間jian隙xi腐fu蝕shi對dui密mi封feng性xing能neng非fei常chang有you害hai。密mi封feng圈quan與yu雙shuang軸zhou之zhi間jian的de凹ao槽cao會hui導dao致zhi補bu償chang環huan無wu法fa軸zhou向xiang位wei移yi，失shi去qu隨sui動dong性xing
，導dao致zhi端duan麵mian分fen離li和he泄xie漏lou。間jian隙xi腐fu蝕shi通tong常chang可ke以yi通tong過guo適shi當dang的de材cai料liao選xuan擇ze和he合he理li的de結jie構gou設she計ji來lai緩huan解jie。比bi如ru選xuan擇ze抗kang間jian隙xi腐fu蝕shi性xing能neng好hao的de材cai料liao；zaijiegoushejizhong
，yingjinkenengbimianyetijijudejianxihesiqu。caiyongzichongxixunhuan，shimifengqiangneidejiezhichuyubuduangenghuanheliudongdezhuangtai，fangzhijiezhichengfendenongdubianhua
；duiyuchangqitingyongdebeng，yingjishipaichujijudeyetideng。bukenengwanquanxiaochujiegoushangdechaju。suoyiyibancaiyongfanghuzhoucheng
，keyizaimifengquananzhuangbuweipentunaifushicailiaolaifangzhi。
　　5.電化學腐蝕。事實上
，固陽機械密封的各種腐蝕形式或多或少都與銅的電化學腐蝕有關。就固陽機械密封摩(mo)擦(ca)副(fu)而(er)言(yan)，它(ta)們(men)經(jing)常(chang)受(shou)到(dao)電(dian)化(hua)學(xue)腐(fu)蝕(shi)的(de)損(sun)害(hai)
，因(yin)為(wei)摩(mo)擦(ca)副(fu)中(zhong)通(tong)常(chang)使(shi)用(yong)不(bu)同(tong)的(de)材(cai)料(liao)。當(dang)它(ta)們(men)處(chu)於(yu)電(dian)解(jie)質(zhi)溶(rong)液(ye)中(zhong)時(shi)，不(bu)同(tong)材(cai)料(liao)接(jie)觸(chu)時(shi)會(hui)出(chu)現(xian)點(dian)耦(ou)合(he)效(xiao)應(ying)，即(ji)一(yi)種(zhong)材(cai)料(liao)的(de)腐(fu)蝕(shi)得(de)到(dao)促(cu)進(jin)，另(ling)一(yi)種(zhong)材(cai)料(liao)的(de)腐(fu)蝕(shi)得(de)到(dao)抑(yi)製(zhi)。例(li)如(ru)

，當(dang)銅(tong)和(he)鎳(nie)鉻(ge)鋼(gang)用(yong)於(yu)氧(yang)化(hua)介(jie)質(zhi)時(shi)，鎳(nie)鎘(ge)鋼(gang)被(bei)電(dian)離(li)和(he)分(fen)解(jie)。鹽(yan)水(shui)、海水、稀鹽酸、稀硫酸等。都是典型的電解質溶液，密封件容易發生電化學腐蝕。所以最好選擇材料或者電位相近的陶瓷，以及玻璃纖維填充的PTFE。