高縣機械密封的腐蝕類型

　　1.整體腐蝕和局部腐蝕。綜合腐蝕，即與介質接觸的零件表麵發生均勻腐蝕
，其特點是零件重量減輕，甚至完全腐蝕

；失去力量；降低硬度。如1Cr18Ni9Ti不bu鏽xiu鋼gang製zhi成cheng的de多duo彈dan簧huang
，在zai稀xi硫liu酸suan中zhong使shi用yong會hui出chu現xian這zhe種zhong情qing況kuang。局ju部bu腐fu蝕shi可ke以yi簡jian單dan地di通tong過guo零ling件jian上shang的de腐fu蝕shi點dian和he孔kong來lai識shi別bie。局ju部bu腐fu蝕shi是shi多duo相xiang合he金jin中zhong的de某mou一yi相xiang或huo單dan相xiang固gu溶rong體ti中zhong的de某mou一yi元yuan素su被bei介jie質zhi選xuan擇ze性xing溶rong解jie的de腐fu蝕shi形xing式shi。如ru鈷gu基ji硬ying質zhi合he金jin在zai高gao溫wen強qiang堿jian條tiao件jian下xia使shi用yong，粘zhan結jie相xiang金jin屬shu鈷gu容rong易yi被bei腐fu蝕shi
，硬ying質zhi相xiang碳tan化hua鎢wu骨gu架jia失shi去qu強qiang度du，在zai機ji械xie力li的de作zuo用yong下xia導dao致zhi晶jing粒li剝bo落luo。作zuo為wei另ling一yi個ge例li子zi，由you於yu遊you離li矽gui的de腐fu蝕shi，反fan應ying燒shao結jie碳tan化hua矽gui的de表biao麵mian顯xian示shi麻ma點dian(PH>10時).
　　腐(fu)蝕(shi)對(dui)密(mi)封(feng)件(jian)的(de)性(xing)能(neng)有(you)很(hen)大(da)影(ying)響(xiang)。由(you)於(yu)密(mi)封(feng)比(bi)主(zhu)機(ji)的(de)零(ling)件(jian)更(geng)小(xiao)，精(jing)度(du)更(geng)高(gao)，所(suo)以(yi)通(tong)常(chang)選(xuan)擇(ze)比(bi)主(zhu)機(ji)密(mi)封(feng)耐(nai)腐(fu)蝕(shi)的(de)材(cai)料(liao)。對(dui)於(yu)與(yu)介(jie)質(zhi)直(zhi)接(jie)接(jie)觸(chu)的(de)密(mi)封(feng)件(jian)，可(ke)參(can)考(kao)相(xiang)關(guan)腐(fu)蝕(shi)手(shou)冊(ce)中(zhong)的(de)數(shu)據(ju)選(xuan)擇(ze)合(he)適(shi)的(de)材(cai)料(liao)。然(ran)而(er)，這(zhe)些(xie)數(shu)據(ju)可(ke)能(neng)與(yu)高縣機械密封係統中使用的條件不一致，因為它們大多是靜態條件下的腐蝕數據，並且工藝流程中的介質包含雜質或二次化合物。經驗表明
，壓力、溫度和滑動速度都會加速腐蝕。隨著溫度的升高
，密封件的腐蝕速率呈指數增長。
　　在zai處chu理li強qiang腐fu蝕shi性xing流liu體ti時shi
，采cai用yong外wai密mi封feng或huo雙shuang端duan密mi封feng可ke以yi最zui大da限xian度du地di減jian少shao腐fu蝕shi對dui密mi封feng的de影ying響xiang，因yin為wei它ta與yu工gong藝yi流liu體ti接jie觸chu的de零ling件jian數shu量liang最zui少shao。這zhe也ye是shi在zai強qiang腐fu蝕shi條tiao件jian下xia選xuan擇ze密mi封feng結jie構gou最zui古gu老lao的de窯yao理li之zhi一yi。
　　2.應力腐蝕。應力腐蝕是金屬材料在應力作用下在腐蝕環境中的腐蝕現象。無論是外載荷還是殘餘應力，都會加劇腐蝕。奧氏體不鏽鋼、tonghejindeng。rongyichanshengyinglifushi。zaiyinglifushiguochengzhong
，yibanzaijinshubiaomianxingchengxuanzexingfushicao
，ranhoujixujubufushi，zuihouzaiyinglizuoyongxiacongcaodichanshengliewen。dianxingdelizishi104型高縣機械密封的傳動套筒
，由1Cr18Ni9Ti製zhi成cheng。在zai氨an水shui泵beng中zhong使shi用yong時shi，傳chuan動dong套tao筒tong的de傳chuan動dong耳er環huan最zui容rong易yi產chan生sheng應ying力li腐fu蝕shi裂lie紋wen
，從cong而er損sun壞huai耳er環huan。所suo以yi把ba凹ao耳er釘ding換huan成cheng實shi心xin耳er片pian可ke以yi防fang止zhi這zhe種zhong應ying力li腐fu蝕shi。
　　3.jiezhifushi。mifengjianheliutizhijiandegaosuyundongdaozhijiechubiaomianshangdeweixiaobujunyun。dangliutiweifushixingjiezhishi
，huijiasumifengjiechumiandehuaxuefanying，youshiyouyi，youshiyouhai。ruguoxingchengdeyanghuacengbeipohuai，jiuhuifashengfushi。mosunhemoshijiaotizuoyongduicailiaozaochengdesunshangchengweimoshi。tongchang
，mosundui高縣機械密封的非主要部件造成的損壞
，如彈簧座、推環、環huan座zuo等deng。並bing不bu能neng迅xun速su反fan映ying密mi封feng性xing能neng的de變bian化hua，但dan卻que是shi摩mo擦ca副fu失shi效xiao的de主zhu要yao形xing式shi之zhi一yi。因yin此ci
，在zai腔qiang體ti的de腐fu蝕shi介jie質zhi中zhong，摩mo擦ca副fu應ying由you耐nai腐fu蝕shi性xing好hao的de材cai料liao製zhi成cheng。例li如ru，使shi用yong99.5%高純度氧化鋁陶瓷或不含遊離矽的熱壓燒結碳化矽。
　　4.jianxifushi。dangjiezhichuyujinshuyujinshuhuofeijinshugoujianzhijian，qiecunzaixiaojianxishi

，youyujiezhichuyutingzhizhuangtai
，jianxineijinshudefushihuijiasu，zhezhongxianxiangchengweijianxifushi。liru高縣機械密封彈簧座與軸之間的溝槽或衝蝕點，補償環輔助密封環與軸之間的溝槽或衝蝕點(這裏當然有微動磨損)jiushidianxingdelizi。yuanyinshijietouneidejiezhichuyutingzhizhuangtai，shidecanyufushifanyingdewuzhinanyijiarujietounei，jietouneidefushichanwunanyixiangwaikuosan。suizhefushidejinxing，jietouzhongdejiezhizaichengfennongduhePHzhishangyuzhenggejiezhiyuelaiyuebutong，daozhijietouzhongjinshubiaomiandefushijiaju。jianxifushiduimifengxingnengfeichangyouhai。mifengquanyushuangzhouzhijiandeaocaohuidaozhibuchanghuanwufazhouxiangweiyi
，shiqusuidongxing，daozhiduanmianfenlihexielou。jianxifushitongchangkeyitongguoshidangdecailiaoxuanzehehelidejiegoushejilaihuanjie。biruxuanzekangjianxifushixingnenghaodecailiao
；zaijiegoushejizhong，yingjinkenengbimianyetijijudejianxihesiqu。caiyongzichongxixunhuan，shimifengqiangneidejiezhichuyubuduangenghuanheliudongdezhuangtai
，fangzhijiezhichengfendenongdubianhua；對dui於yu長chang期qi停ting用yong的de泵beng，應ying及ji時shi排pai出chu積ji聚ju的de液ye體ti等deng。不bu可ke能neng完wan全quan消xiao除chu結jie構gou上shang的de差cha距ju。所suo以yi一yi般ban采cai用yong防fang護hu軸zhou承cheng
，可ke以yi在zai密mi封feng圈quan安an裝zhuang部bu位wei噴pen塗tu耐nai腐fu蝕shi材cai料liao來lai防fang止zhi。
　　5.電化學腐蝕。事實上，高縣機械密封的各種腐蝕形式或多或少都與銅的電化學腐蝕有關。就高縣機械密封摩mo擦ca副fu而er言yan，它ta們men經jing常chang受shou到dao電dian化hua學xue腐fu蝕shi的de損sun害hai
，因yin為wei摩mo擦ca副fu中zhong通tong常chang使shi用yong不bu同tong的de材cai料liao。當dang它ta們men處chu於yu電dian解jie質zhi溶rong液ye中zhong時shi，不bu同tong材cai料liao接jie觸chu時shi會hui出chu現xian點dian耦ou合he效xiao應ying，即ji一yi種zhong材cai料liao的de腐fu蝕shi得de到dao促cu進jin
，另ling一yi種zhong材cai料liao的de腐fu蝕shi得de到dao抑yi製zhi。例li如ru，當dang銅tong和he鎳nie鉻ge鋼gang用yong於yu氧yang化hua介jie質zhi時shi，鎳nie鎘ge鋼gang被bei電dian離li和he分fen解jie。鹽yan水shui
、海水、稀鹽酸、稀硫酸等。都是典型的電解質溶液
，密封件容易發生電化學腐蝕。所以最好選擇材料或者電位相近的陶瓷
，以及玻璃纖維填充的PTFE。