發布時間：2026-04-28 20:38:02 人氣：307763 來源：川工密封
1.整體腐蝕和局部腐蝕。綜合腐蝕，即與介質接觸的零件表麵發生均勻腐蝕，其特點是零件重量減輕，甚至完全腐蝕；失去力量；降低硬度。如1Cr18Ni9Tibuxiugangzhichengdeduodanhuang，zaixiliusuanzhongshiyonghuichuxianzhezhongqingkuang。jubufushikeyijiandanditongguolingjianshangdefushidianhekonglaishibie。jubufushishiduoxianghejinzhongdemouyixianghuodanxianggurongtizhongdemouyiyuansubeijiezhixuanzexingrongjiedefushixingshi。rugujiyingzhihejinzaigaowenqiangjiantiaojianxiashiyong，zhanjiexiangjinshugurongyibeifushi，yingzhixiangtanhuawugujiashiquqiangdu，zaijixielidezuoyongxiadaozhijingliboluo。zuoweilingyigelizi，youyuyouliguidefushi，fanyingshaojietanhuaguidebiaomianxianshimadian(PH>10時).
腐fu蝕shi對dui密mi封feng件jian的de性xing能neng有you很hen大da影ying響xiang。由you於yu密mi封feng比bi主zhu機ji的de零ling件jian更geng小xiao，精jing度du更geng高gao，所suo以yi通tong常chang選xuan擇ze比bi主zhu機ji密mi封feng耐nai腐fu蝕shi的de材cai料liao。對dui於yu與yu介jie質zhi直zhi接jie接jie觸chu的de密mi封feng件jian，可ke參can考kao相xiang關guan腐fu蝕shi手shou冊ce中zhong的de數shu據ju選xuan擇ze合he適shi的de材cai料liao。然ran而er，這zhe些xie數shu據ju可ke能neng與yu長子機械密封係統中使用的條件不一致，因為它們大多是靜態條件下的腐蝕數據，並且工藝流程中的介質包含雜質或二次化合物。經驗表明，壓力、溫度和滑動速度都會加速腐蝕。隨著溫度的升高，密封件的腐蝕速率呈指數增長。
zaichuliqiangfushixingliutishi，caiyongwaimifenghuoshuangduanmifengkeyizuidaxiandudijianshaofushiduimifengdeyingxiang，yinweitayugongyiliutijiechudelingjianshuliangzuishao。zheyeshizaiqiangfushitiaojianxiaxuanzemifengjiegouzuigulaodeyaolizhiyi。
2.應力腐蝕。應力腐蝕是金屬材料在應力作用下在腐蝕環境中的腐蝕現象。無論是外載荷還是殘餘應力，都會加劇腐蝕。奧氏體不鏽鋼、銅tong合he金jin等deng。容rong易yi產chan生sheng應ying力li腐fu蝕shi。在zai應ying力li腐fu蝕shi過guo程cheng中zhong，一yi般ban在zai金jin屬shu表biao麵mian形xing成cheng選xuan擇ze性xing腐fu蝕shi槽cao，然ran後hou繼ji續xu局ju部bu腐fu蝕shi，最zui後hou在zai應ying力li作zuo用yong下xia從cong槽cao底di產chan生sheng裂lie紋wen。典dian型xing的de例li子zi是shi104型長子機械密封的傳動套筒，由1Cr18Ni9Ti製(zhi)成(cheng)。在(zai)氨(an)水(shui)泵(beng)中(zhong)使(shi)用(yong)時(shi)，傳(chuan)動(dong)套(tao)筒(tong)的(de)傳(chuan)動(dong)耳(er)環(huan)最(zui)容(rong)易(yi)產(chan)生(sheng)應(ying)力(li)腐(fu)蝕(shi)裂(lie)紋(wen)，從(cong)而(er)損(sun)壞(huai)耳(er)環(huan)。所(suo)以(yi)把(ba)凹(ao)耳(er)釘(ding)換(huan)成(cheng)實(shi)心(xin)耳(er)片(pian)可(ke)以(yi)防(fang)止(zhi)這(zhe)種(zhong)應(ying)力(li)腐(fu)蝕(shi)。
3.介jie質zhi腐fu蝕shi。密mi封feng件jian和he流liu體ti之zhi間jian的de高gao速su運yun動dong導dao致zhi接jie觸chu表biao麵mian上shang的de微wei小xiao不bu均jun勻yun。當dang流liu體ti為wei腐fu蝕shi性xing介jie質zhi時shi，會hui加jia速su密mi封feng接jie觸chu麵mian的de化hua學xue反fan應ying，有you時shi有you益yi，有you時shi有you害hai。如ru果guo形xing成cheng的de氧yang化hua層ceng被bei破po壞huai，就jiu會hui發fa生sheng腐fu蝕shi。磨mo損sun和he磨mo蝕shi交jiao替ti作zuo用yong對dui材cai料liao造zao成cheng的de損sun傷shang稱cheng為wei磨mo蝕shi。通tong常chang，磨mo損sun對dui長子機械密封的非主要部件造成的損壞，如彈簧座、推環、環(huan)座(zuo)等(deng)。並(bing)不(bu)能(neng)迅(xun)速(su)反(fan)映(ying)密(mi)封(feng)性(xing)能(neng)的(de)變(bian)化(hua)，但(dan)卻(que)是(shi)摩(mo)擦(ca)副(fu)失(shi)效(xiao)的(de)主(zhu)要(yao)形(xing)式(shi)之(zhi)一(yi)。因(yin)此(ci)，在(zai)腔(qiang)體(ti)的(de)腐(fu)蝕(shi)介(jie)質(zhi)中(zhong)，摩(mo)擦(ca)副(fu)應(ying)由(you)耐(nai)腐(fu)蝕(shi)性(xing)好(hao)的(de)材(cai)料(liao)製(zhi)成(cheng)。例(li)如(ru)，使(shi)用(yong)99.5%高純度氧化鋁陶瓷或不含遊離矽的熱壓燒結碳化矽。
4.間(jian)隙(xi)腐(fu)蝕(shi)。當(dang)介(jie)質(zhi)處(chu)於(yu)金(jin)屬(shu)與(yu)金(jin)屬(shu)或(huo)非(fei)金(jin)屬(shu)構(gou)件(jian)之(zhi)間(jian)，且(qie)存(cun)在(zai)小(xiao)間(jian)隙(xi)時(shi)，由(you)於(yu)介(jie)質(zhi)處(chu)於(yu)停(ting)滯(zhi)狀(zhuang)態(tai)，間(jian)隙(xi)內(nei)金(jin)屬(shu)的(de)腐(fu)蝕(shi)會(hui)加(jia)速(su)，這(zhe)種(zhong)現(xian)象(xiang)稱(cheng)為(wei)間(jian)隙(xi)腐(fu)蝕(shi)。例(li)如(ru)長子機械密封彈簧座與軸之間的溝槽或衝蝕點，補償環輔助密封環與軸之間的溝槽或衝蝕點(這裏當然有微動磨損)就jiu是shi典dian型xing的de例li子zi。原yuan因yin是shi接jie頭tou內nei的de介jie質zhi處chu於yu停ting滯zhi狀zhuang態tai，使shi得de參can與yu腐fu蝕shi反fan應ying的de物wu質zhi難nan以yi加jia入ru接jie頭tou內nei，接jie頭tou內nei的de腐fu蝕shi產chan物wu難nan以yi向xiang外wai擴kuo散san。隨sui著zhe腐fu蝕shi的de進jin行xing，接jie頭tou中zhong的de介jie質zhi在zai成cheng分fen濃nong度du和hePHzhishangyuzhenggejiezhiyuelaiyuebutong，daozhijietouzhongjinshubiaomiandefushijiaju。jianxifushiduimifengxingnengfeichangyouhai。mifengquanyushuangzhouzhijiandeaocaohuidaozhibuchanghuanwufazhouxiangweiyi，shiqusuidongxing，daozhiduanmianfenlihexielou。jianxifushitongchangkeyitongguoshidangdecailiaoxuanzehehelidejiegoushejilaihuanjie。biruxuanzekangjianxifushixingnenghaodecailiao；zaijiegoushejizhong，yingjinkenengbimianyetijijudejianxihesiqu。caiyongzichongxixunhuan，shimifengqiangneidejiezhichuyubuduangenghuanheliudongdezhuangtai，fangzhijiezhichengfendenongdubianhua；duiyuchangqitingyongdebeng，yingjishipaichujijudeyetideng。bukenengwanquanxiaochujiegoushangdechaju。suoyiyibancaiyongfanghuzhoucheng，keyizaimifengquananzhuangbuweipentunaifushicailiaolaifangzhi。
5.電化學腐蝕。事實上，長子機械密封的各種腐蝕形式或多或少都與銅的電化學腐蝕有關。就長子機械密封摩mo擦ca副fu而er言yan，它ta們men經jing常chang受shou到dao電dian化hua學xue腐fu蝕shi的de損sun害hai，因yin為wei摩mo擦ca副fu中zhong通tong常chang使shi用yong不bu同tong的de材cai料liao。當dang它ta們men處chu於yu電dian解jie質zhi溶rong液ye中zhong時shi，不bu同tong材cai料liao接jie觸chu時shi會hui出chu現xian點dian耦ou合he效xiao應ying，即ji一yi種zhong材cai料liao的de腐fu蝕shi得de到dao促cu進jin，另ling一yi種zhong材cai料liao的de腐fu蝕shi得de到dao抑yi製zhi。例li如ru，當dang銅tong和he鎳nie鉻ge鋼gang用yong於yu氧yang化hua介jie質zhi時shi，鎳nie鎘ge鋼gang被bei電dian離li和he分fen解jie。鹽yan水shui、海水、稀鹽酸、稀硫酸等。都是典型的電解質溶液，密封件容易發生電化學腐蝕。所以最好選擇材料或者電位相近的陶瓷，以及玻璃纖維填充的PTFE。
