白雲機械密封的腐蝕類型

　　1.整體腐蝕和局部腐蝕。綜合腐蝕，即與介質接觸的零件表麵發生均勻腐蝕，其特點是零件重量減輕，甚至完全腐蝕

；失去力量；降低硬度。如1Cr18Ni9Ti不(bu)鏽(xiu)鋼(gang)製(zhi)成(cheng)的(de)多(duo)彈(dan)簧(huang)，在(zai)稀(xi)硫(liu)酸(suan)中(zhong)使(shi)用(yong)會(hui)出(chu)現(xian)這(zhe)種(zhong)情(qing)況(kuang)。局(ju)部(bu)腐(fu)蝕(shi)可(ke)以(yi)簡(jian)單(dan)地(di)通(tong)過(guo)零(ling)件(jian)上(shang)的(de)腐(fu)蝕(shi)點(dian)和(he)孔(kong)來(lai)識(shi)別(bie)。局(ju)部(bu)腐(fu)蝕(shi)是(shi)多(duo)相(xiang)合(he)金(jin)中(zhong)的(de)某(mou)一(yi)相(xiang)或(huo)單(dan)相(xiang)固(gu)溶(rong)體(ti)中(zhong)的(de)某(mou)一(yi)元(yuan)素(su)被(bei)介(jie)質(zhi)選(xuan)擇(ze)性(xing)溶(rong)解(jie)的(de)腐(fu)蝕(shi)形(xing)式(shi)。如(ru)鈷(gu)基(ji)硬(ying)質(zhi)合(he)金(jin)在(zai)高(gao)溫(wen)強(qiang)堿(jian)條(tiao)件(jian)下(xia)使(shi)用(yong)，粘(zhan)結(jie)相(xiang)金(jin)屬(shu)鈷(gu)容(rong)易(yi)被(bei)腐(fu)蝕(shi)，硬(ying)質(zhi)相(xiang)碳(tan)化(hua)鎢(wu)骨(gu)架(jia)失(shi)去(qu)強(qiang)度(du)
，在(zai)機(ji)械(xie)力(li)的(de)作(zuo)用(yong)下(xia)導(dao)致(zhi)晶(jing)粒(li)剝(bo)落(luo)。作(zuo)為(wei)另(ling)一(yi)個(ge)例(li)子(zi)
，由(you)於(yu)遊(you)離(li)矽(gui)的(de)腐(fu)蝕(shi)，反(fan)應(ying)燒(shao)結(jie)碳(tan)化(hua)矽(gui)的(de)表(biao)麵(mian)顯(xian)示(shi)麻(ma)點(dian)(PH>10時).
　　腐fu蝕shi對dui密mi封feng件jian的de性xing能neng有you很hen大da影ying響xiang。由you於yu密mi封feng比bi主zhu機ji的de零ling件jian更geng小xiao
，精jing度du更geng高gao
，所suo以yi通tong常chang選xuan擇ze比bi主zhu機ji密mi封feng耐nai腐fu蝕shi的de材cai料liao。對dui於yu與yu介jie質zhi直zhi接jie接jie觸chu的de密mi封feng件jian

，可ke參can考kao相xiang關guan腐fu蝕shi手shou冊ce中zhong的de數shu據ju選xuan擇ze合he適shi的de材cai料liao。然ran而er，這zhe些xie數shu據ju可ke能neng與yu白雲機械密封係統中使用的條件不一致，因為它們大多是靜態條件下的腐蝕數據，並且工藝流程中的介質包含雜質或二次化合物。經驗表明
，壓力、溫度和滑動速度都會加速腐蝕。隨著溫度的升高
，密封件的腐蝕速率呈指數增長。
　　zaichuliqiangfushixingliutishi，caiyongwaimifenghuoshuangduanmifengkeyizuidaxiandudijianshaofushiduimifengdeyingxiang，yinweitayugongyiliutijiechudelingjianshuliangzuishao。zheyeshizaiqiangfushitiaojianxiaxuanzemifengjiegouzuigulaodeyaolizhiyi。
　　2.應力腐蝕。應力腐蝕是金屬材料在應力作用下在腐蝕環境中的腐蝕現象。無論是外載荷還是殘餘應力，都會加劇腐蝕。奧氏體不鏽鋼
、tonghejindeng。rongyichanshengyinglifushi。zaiyinglifushiguochengzhong
，yibanzaijinshubiaomianxingchengxuanzexingfushicao，ranhoujixujubufushi
，zuihouzaiyinglizuoyongxiacongcaodichanshengliewen。dianxingdelizishi104型白雲機械密封的傳動套筒，由1Cr18Ni9Ti製zhi成cheng。在zai氨an水shui泵beng中zhong使shi用yong時shi，傳chuan動dong套tao筒tong的de傳chuan動dong耳er環huan最zui容rong易yi產chan生sheng應ying力li腐fu蝕shi裂lie紋wen
，從cong而er損sun壞huai耳er環huan。所suo以yi把ba凹ao耳er釘ding換huan成cheng實shi心xin耳er片pian可ke以yi防fang止zhi這zhe種zhong應ying力li腐fu蝕shi。
　　3.介jie質zhi腐fu蝕shi。密mi封feng件jian和he流liu體ti之zhi間jian的de高gao速su運yun動dong導dao致zhi接jie觸chu表biao麵mian上shang的de微wei小xiao不bu均jun勻yun。當dang流liu體ti為wei腐fu蝕shi性xing介jie質zhi時shi
，會hui加jia速su密mi封feng接jie觸chu麵mian的de化hua學xue反fan應ying，有you時shi有you益yi，有you時shi有you害hai。如ru果guo形xing成cheng的de氧yang化hua層ceng被bei破po壞huai
，就jiu會hui發fa生sheng腐fu蝕shi。磨mo損sun和he磨mo蝕shi交jiao替ti作zuo用yong對dui材cai料liao造zao成cheng的de損sun傷shang稱cheng為wei磨mo蝕shi。通tong常chang


，磨mo損sun對dui白雲機械密封的非主要部件造成的損壞
，如彈簧座、推環、huanzuodeng。bingbunengxunsufanyingmifengxingnengdebianhua，danqueshimocafushixiaodezhuyaoxingshizhiyi。yinci，zaiqiangtidefushijiezhizhong，mocafuyingyounaifushixinghaodecailiaozhicheng。liru，shiyong99.5%高純度氧化鋁陶瓷或不含遊離矽的熱壓燒結碳化矽。
　　4.間jian隙xi腐fu蝕shi。當dang介jie質zhi處chu於yu金jin屬shu與yu金jin屬shu或huo非fei金jin屬shu構gou件jian之zhi間jian，且qie存cun在zai小xiao間jian隙xi時shi
，由you於yu介jie質zhi處chu於yu停ting滯zhi狀zhuang態tai

，間jian隙xi內nei金jin屬shu的de腐fu蝕shi會hui加jia速su，這zhe種zhong現xian象xiang稱cheng為wei間jian隙xi腐fu蝕shi。例li如ru白雲機械密封彈簧座與軸之間的溝槽或衝蝕點

，補償環輔助密封環與軸之間的溝槽或衝蝕點(這裏當然有微動磨損)就jiu是shi典dian型xing的de例li子zi。原yuan因yin是shi接jie頭tou內nei的de介jie質zhi處chu於yu停ting滯zhi狀zhuang態tai，使shi得de參can與yu腐fu蝕shi反fan應ying的de物wu質zhi難nan以yi加jia入ru接jie頭tou內nei，接jie頭tou內nei的de腐fu蝕shi產chan物wu難nan以yi向xiang外wai擴kuo散san。隨sui著zhe腐fu蝕shi的de進jin行xing，接jie頭tou中zhong的de介jie質zhi在zai成cheng分fen濃nong度du和hePH值zhi上shang與yu整zheng個ge介jie質zhi越yue來lai越yue不bu同tong，導dao致zhi接jie頭tou中zhong金jin屬shu表biao麵mian的de腐fu蝕shi加jia劇ju。間jian隙xi腐fu蝕shi對dui密mi封feng性xing能neng非fei常chang有you害hai。密mi封feng圈quan與yu雙shuang軸zhou之zhi間jian的de凹ao槽cao會hui導dao致zhi補bu償chang環huan無wu法fa軸zhou向xiang位wei移yi
，失shi去qu隨sui動dong性xing，導dao致zhi端duan麵mian分fen離li和he泄xie漏lou。間jian隙xi腐fu蝕shi通tong常chang可ke以yi通tong過guo適shi當dang的de材cai料liao選xuan擇ze和he合he理li的de結jie構gou設she計ji來lai緩huan解jie。比bi如ru選xuan擇ze抗kang間jian隙xi腐fu蝕shi性xing能neng好hao的de材cai料liao；zaijiegoushejizhong，yingjinkenengbimianyetijijudejianxihesiqu。caiyongzichongxixunhuan，shimifengqiangneidejiezhichuyubuduangenghuanheliudongdezhuangtai，fangzhijiezhichengfendenongdubianhua；對dui於yu長chang期qi停ting用yong的de泵beng
，應ying及ji時shi排pai出chu積ji聚ju的de液ye體ti等deng。不bu可ke能neng完wan全quan消xiao除chu結jie構gou上shang的de差cha距ju。所suo以yi一yi般ban采cai用yong防fang護hu軸zhou承cheng
，可ke以yi在zai密mi封feng圈quan安an裝zhuang部bu位wei噴pen塗tu耐nai腐fu蝕shi材cai料liao來lai防fang止zhi。
　　5.電化學腐蝕。事實上
，白雲機械密封的各種腐蝕形式或多或少都與銅的電化學腐蝕有關。就白雲機械密封mocafueryan，tamenjingchangshoudaodianhuaxuefushidesunhai
，yinweimocafuzhongtongchangshiyongbutongdecailiao。dangtamenchuyudianjiezhirongyezhongshi，butongcailiaojiechushihuichuxiandianouhexiaoying
，jiyizhongcailiaodefushidedaocujin，lingyizhongcailiaodefushidedaoyizhi。liru
，dangtongheniegegangyongyuyanghuajiezhishi，niegegangbeidianlihefenjie。yanshui、海水、稀鹽酸、稀硫酸等。都是典型的電解質溶液
，密封件容易發生電化學腐蝕。所以最好選擇材料或者電位相近的陶瓷，以及玻璃纖維填充的PTFE。